| # | Date Aired | Episode Title | DVD # | Rating | Go |
| 31 | 09/17/66 | Anatomy Of A Lover | DVD #2 | 6.66 | GO |
| 32 | 09/24/66 | Strike While The Agent Is Hot | DVD #2 | 6.66 | GO |
| 33 | 10/01/66 | A Spy For A Spy | DVD #2 | 8.00 | GO |
| 34 | 10/08/66 | The Only Way To Die | DVD #2 | 5.00 | GO |
| 35 | 10/15/66 | Maxwell Smart Alais Jimmy Ballentine | DVD #2 | 4.00 | GO |
| 36 | 10/22/66 | Cassablanca | DVD #2 | 6.66 | GO |
| 37 | 10/29/66 | The Decoy | DVD #2 | 6.66 | GO |
| 38 | 11/05/66 | Hoo Done It | DVD #2 | 6.66 | GO |
| 39 | 11/12/66 | Rub-A-Dub-Dub, Three Spies In A Sub | DVD #2 | 7.00 | GO |
| 40 | 11/19/66 | The Greatest Spy On Earth | DVD #3 | 6.66 | GO |
| 41 | 11/26/66 | Island Of The Darned | DVD #3 | 4.00 | GO |
| 42 | 12/03/66 | Bronzefinger | DVD #3 | 4.00 | GO |
| 43 | 12/10/66 | Perils In A Pet Shop | DVD #3 | 6.66 | GO |
| 44 | 12/24/66 | The Whole Tooth and ... | DVD #3 | 4.00 | GO |
| 45 | 12/31/66 | Kiss Of Death | DVD #3 | 4.00 | GO |
| 46 | 01/07/67 | It Takes One To Know One | DVD #3 | 7.00 | GO |
| 47 | 01/14/67 | Someone Down Here Hates Me | DVD #3 | 7.00 | GO |
| 48 | 01/21/67 | Cutback At Control | DVD #3 | 6.66 | GO |
| 49 | 01/28/67 | The Mummy | DVD #3 | 5.00 | GO |
| 50 | 02/04/67C | The Girls From Kaos | DVD #3 | 6.66 | GO |
| 49 | 02/11/67 | The Man From Yenta | DVD #3 | 8.00 | GO |
| 52 | 02/18/67 | SmartFit The Battle Of Jerico | DVD #3 | 4.00 | GO |
| 53 | 02/25/67 | Where-What-How-Who Am I ? | DVD #3 | 6.66 | GO |
| 54 | 03/04/67 | The Expendable Agent | DVD #3 | 6.66 | GO |
| 55 | 03/11/67 | How To Succeed In The Spy Business Without Really Trying | DVD #3 | 7.00 | GO |
| 56 | 03/25/67 | Appointment In Sahara | DVD #3 | 4.00 | GO |
| 57 | 04/01/67 | Pussycats Galore | DVD #3 | 4.00 | GO |
| 58 | 04/08/67 | A Man Called Smart, Part I | DVD #3 | 8.00 | GO |
| 59 | 04/15/67 | A Man Called Smart, Part II | DVD #3 | 8.00 | GO |
| 60 | 04/22/67 | A Man Called Smart, Part III | DVD #4 | 8.00 | GO |